Automated Extraction of a Five‐Year LA‐ICP‐MS Trace Element Data Set of Ten Common Glass and Carbonate Reference Materials: Long‐Term Data Quality,Optimisation and Laser Cell Homogeneity          下载免费PDF全文

David Evans  Wolfgang Müller 《Geostandards and Geoanalytical Research》2018,42(2):159-188

LA‐ICP‐MS is increasingly applied to obtain quantitative multi‐element data with minimal sample preparation, usually achieved by calibration using reference materials (RMs). However, some ubiquitous RMs, for example the NIST SRM 61× series glasses, suffer from reported value uncertainties for certain elements. Moreover, no long‐term data set of analyses conducted over a range of ablation and tuning conditions exists. Thus, there has been little rigorous examination of the extent to which offsets between measured and reported values are the result of error in these values rather than analytically induced fractionation. We present new software (‘LA‐MINE’), capable of extracting LA‐ICP‐MS data with no user input, and apply this to our system, yielding over 5 years of data (~ 5700 analyses of ten glass and carbonate RMs). We examine the relative importance of systematic analytical bias and possible error in reported values through a mass‐specific breakdown of fourteen of the most commonly determined elements. Furthermore, these data, obtained under a wide range of different ablation conditions, enable specific recommendations of how data quality may be improved, for example the role of diatomic gas, the effect of differential inter‐glass fractionation factors and choice of transport tubing material. Finally, these data demonstrate that the two‐volume Laurin ablation cell is characterised by no discernible spatial heterogeneity in measured trace element ratios.  相似文献   

Twenty-five years of spectral UV-B measurements over Canada,Europe and Japan: Trends and effects from changes in ozone,aerosols, clouds,and surface reflectivity     

《Comptes Rendus Geoscience》2018,350(7):393-402

Spectral UV records of solar irradiance at stations over Europe, Canada, and Japan were used to study long-term trends at 307.5 nm for a 25-year period, from 1992 to 2016. Ground-based measurements of total ozone, as well as satellite measurements of the Aerosol Index, the Total Cloud Cover and the surface reflectivity were also used in order to attribute the estimated changes of the UV to the corresponding changes of these factors. The present study shows that over the Northern Hemisphere, the long-term changes in UV-B radiation reaching the Earth's surface vary significantly over different locations, and that the main drivers of these variations are changes in aerosols and total ozone. At high latitudes, part of the observed changes may also be attributed to changes in the surface reflectivity. Over Japan, the UV-B irradiance at 307.5 nm has increased significantly by ∼3%/decade during the past 25 years, possibly due to the corresponding significant decrease of its absorption by aerosols. It was found that the greatest part of this increase took place before the mid-2000s. The only European station, over which UV radiation increases significantly, is that of Thessaloniki, Greece. Analysis of the clear-sky irradiance for the particular station shows increasing irradiance at 307.5 nm by ∼3.5%/decade during the entire period of study, with an increasing rate of change during the last decade, possibly again due to the decreasing absorption by aerosols.  相似文献   

光压模型对GPS精密单点定位的影响     

祝会忠  朱爽  唐龙江 《大地测量与地球动力学》2022,42(9):910-913

利用全球120个跟踪站2019年doy110~139观测数据进行GPS精密定轨;然后采用ECOM1、ECOM1+BW、ECOM1+ABW等3种光压模型,使用7个未参与定轨的测站进行PPP实验。结果表明,ECOM1+ABW组合模型轨道精度最高,非地影期三维轨道精度优于4 cm;对于静态PPP,收敛后水平方向精度优于0.8 cm,垂直方向精度优于1.2 cm;对于动态PPP,收敛时间在30 min左右,收敛后水平方向精度优于1.4 cm,垂直方向精度优于2.0 cm。  相似文献   

Impacts of Aerosol-Radiation Interactions on the Wintertime Particulate Pollution under Different Synoptic Patterns in the Guanzhong Basin,China     

Naifang BEI  Xia LI  Qiyuan WANG  Suixin LIU  Jiarui WU  Jiayi LIANG  Lang LIU  Ruonan WANG  Guohui LI 《大气科学进展》2021,38(7):1141-1152

The effects of aerosol–radiation interactions(ARI) are not only important for regional and global climate, but they can also drive particulate matter(PM) pollution. In this study, the ARI contribution to the near-surface fine PM(PM2.5)concentrations in the Guanzhong Basin(GZB) is evaluated under four unfavorable synoptic patterns, including "northlow", "transition", "southeast-trough", and "inland-high", based on WRF-Chem model simulations of a persistent heavy PM pollution episode in January 2019. Simulations show that ARI consistently decreases both solar radiation reaching down to the surface(SWDOWN) and surface temperature(TSFC), which then reduces wind speed, induces sinking motion,and influences cloud formation in the GZB. However, large differences under the four synoptic patterns still exist. The average reductions of SWDOWN and daytime TSFC in the GZB range from 15.2% and 1.04°C in the case of the"transition" pattern to 26.7% and 1.69°C in the case of the "north-low" pattern, respectively. Furthermore, ARI suppresses the development of the planetary boundary layer(PBL), with the decrease of PBL height(PBLH) varying from 18.7% in the case of the "transition" pattern to 32.0% in the case of the "north-low" pattern. The increase of daytime near-surface PM2.5 in the GZB due to ARI is 12.0%, 8.1%, 9.5%, and 9.7% under the four synoptic patterns, respectively. Ensemble analyses also reveal that when near-surface PM2.5 concentrations are low, ARI tends to lower PM2.5 concentrations with decreased PBLH, which is caused by enhanced divergence or a transition from divergence to convergence in an area. ARI contributes 15%–25% toward the near-surface PM2.5 concentrations during the severe PM pollution period under the four synoptic patterns.  相似文献   

强雷暴天气的闪电和雷达回波特征个例分析     

张春燕  刘霞  高文俊  周宝琴  张国平 《热带气象学报》2021,37(3):419-426

利用粤港澳闪电定位系统、广州多普勒天气雷达和自动气象站等资料, 分析了2017年6月2日发生在广州市中北部的一次强雷暴天气过程的地闪变化特征及闪电与雷达回波特征的关系。(1)本次强雷暴天气是华南一起典型的以西南急流和切变线为环流背景的强对流天气过程。在整个雷暴生命史中以负地闪为主, 占69.3%;正闪在雷暴发展的初始和结束阶段占比较大。(2)闪电频数分布与强雷达回波区域存在着较好的对应关系, 闪电活动位置稍有提前, 地闪频数峰值的时间比雷达回波峰值时间平均提前了11.1 min。(3)回波顶高是产生闪电的先决条件, 闪电较多分布在回波顶高9~15 km范围内, 地闪频数峰值落后于回波顶高峰值12~18 min。   相似文献   

新疆及邻区体波震级初步分析研究          下载免费PDF全文

冉慧敏  李文倩  上官文明 《中国地震》2022,38(1):91-101

依据《地震震级的规定（GB 17740—2017）》,分析了2009—2017年新疆地震台网所记录的新疆及邻区476次中深源地震事件,测定了13601个m_b（短周期体波震级）和12035个m_B（BB）（宽频带体波震级）的数据样本,回归分析m_b和m_B（BB）得到回归方程及量规函数,结果显示m_b和m_B（BB）相关系数为0.966,表明两者显著相关。因此,建议对于中强型中深源地震可以直接从原始速度型宽频带数字地震记录上测定长周期体波震级m_B（BB）,提高地震速报测定的速度和精度。通过震级偏差统计和台站场地响应计算,分析新疆地震台网中的XKR、HTA、ATS和KSZ等地震台站震级偏差较大的原因为砂岩、灰岩、砂土层等类型的台基放大了场地响应,说明台基类型对体波震级偏差的影响较大。与NEIC测定的体波震级对比时,发现新疆地震台网测定体波震级平均偏大0.42级,且偏差随着震源深度的增加有增大的趋势。  相似文献   

Advances and limitations in establishing a contiguous high-resolution atmospheric radiocarbon record derived from subfossil kauri tree rings for the interval 60–27 cal kyr BP     

《Quaternary Geochronology》2022

Radiocarbon dating is the most widely applied and reliable dating technique for providing chronological control during Marine Isotope Stage 3 (MIS3; ∼60–27 cal kyr BP). Past variations in the atmospheric concentration of radiocarbon mean a calibration curve is required. IntCal20 and SHCal20 calibration curves covering MIS3 are presently largely based on non-atmospheric records which, in combination with larger radiocarbon (¹⁴C) dating uncertainties, results in significant smoothing and reduced resolution in calibration curve structure. Floating tree ring radiocarbon chronologies that are wiggle-matched to other palaeo records (particularly to Hulu Cave speleothems) have the potential to provide detailed structure to the MIS3 portion of extant calibration curves. New Zealand subfossil kauri (Agathis australis) trees are long-lived and are useful for constructing temporally-floating MIS3 atmospheric radiocarbon datasets. This paper presents extant and emerging data from several important Northland subfossil kauri locations (Omaha, Babylon Coast, Bream Bay, Kai Iwi Lakes, Mangawhai). We show the span of seven floating MIS3 kauri sequences (individual trees and chronologies) from which sequential radiocarbon series covering a total of 7556 years is now in development (representing 23% of the period 60–27 cal kyr BP). We also report radiocarbon dates for an additional 34 ancient kauri from MIS3 that can provide additional coverage. After these floating subfossil wood sequences have been produced, close to 40% of MIS3 (12,420 years) will be covered by contiguous subfossil kauri radiocarbon measurements. Based on our findings, we discuss the prospects and limitations for obtaining a highly resolved and precise atmospheric radiocarbon calibration curve comprehensively covering MIS3 using subfossil kauri.  相似文献   

锆石辐射损伤测年方法研究进展与应用     

范明璞  柳小明  孙圣思 《地质论评》2022,68(5):2022102003-2022102003

锆石辐射损伤测年是一种新兴的低温热年代学方法（封闭温度为~230 ± 25 ℃）,其原理是依据拉曼半高宽（ν3）计算出锆石所累积的α通量,结合U、Th含量,得出锆石辐射损伤的累积时间,即锆石辐射损伤年龄。相较于其他低温年代学方法,锆石辐射损伤测年具有测试简便、高效、低成本、双（多）定年等优势,在地学研究中展现出广泛的应用前景,现已成功应用于示踪物源区和揭示岩体热事件等领域。然而,该方法尚存几个关键问题有待解决,例如,微区测试的空间不匹配性、封闭温度存有争议、较大的年龄偏差等,这无疑阻碍其在地球科学领域中更进一步的推广和应用。本文系统地介绍了锆石辐射损伤测年方法的起源、原理和测试方法,总结了相关应用的重要进展,阐述了锆石辐射损伤测年方法的尚存问题,并对该方法的发展趋势作以展望,以期为年代学的发展提供新的技术手段。  相似文献   

海南岛北部全新世最大海侵古岸线的发现及其意义     

张磊  王超群  麦发海  贾丽云  孙东霞  张耀玲  杨肖肖  韩建恩  韩帅  吕同艳  杜建军  赵希涛  胡道功 《地质论评》2022,68(6):2269-2276

全新世大暖期的最大海侵对沿海地区具有深刻影响,但是海南岛北部全新世的最大海侵范围研究较少。本研究利用高精度DEM数据解译以及野外钻探验证,发现海南岛北部全新世精确的最大海侵古岸线空间展布位置,其总面积约260 km2,其中约115 km2属于现今的江东新区规划建设范围内,占整个江东新区规划面积的38%。海南岛北部全新世最大海侵古海岸线的发现,不仅对理解南海全新世高海平面特征及规律提供琼北地区新证据,并且对海南自贸区（江东新区）应对未来海平面升高问题提供背景参照。  相似文献   

Extinctions, Morphological Gaps, Major Transitions, Stem Groups, and the Origin of Major Clades, with a Focus on Early Animals     

XIAO Shuhai 《《地质学报》英文版》2022,96(6):1821-1829

Systematic extinctions can leave major morphological gaps between living crown-group clades. Such morphological gaps would be perceived, from a neontological point of view, as major evolutionary transitions. In order to fill these morphological gaps and to map the evolutionary steps toward major evolutionary transitions, we need to integrate extinct stem-group taxa in phylogenetic studies. However, the recognition of stem group has not been widely adopted in the study of early animal fossils, despite that all fossils are stem groups at one level or another. Part of the difficulty is that stem groups may not have all features that collectively diagnose the respective crown group, and they can have unique (autapomorphic) features, making them tantalizingly similar to and frustratingly different from the crown group (e.g., stem-group eukaryotes can be prokaryotic and stem-group animals can be protistan). The need to embrace stem groups and to implement the PhyloCode, in order to achieve phylogenetic clarity and to offer key paleontological insights into the origin and early animal evolution, is illustrated in debates on several controversial Ediacaran and Cambrian fossils.  相似文献